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NCT 91

COOLING TOWER WATER QUALITY PARAMETERS & CONTROL

ParameterTarget RangeReason / Effect
pH7.5 – 9.0Low pH: Corrosion. High pH: Scaling, reduced biocide efficacy.
Conductivity (TDS)Controlled via COCDirect measure of dissolved solids. Used to control blowdown.
Alkalinity (M-Alk)50-300 ppm as CaCO₃Buffer for pH, relates to scaling potential (Langelier Index).
Calcium Hardness< 500 ppm as CaCO₃Key scaling ion.
Silica (SiO₂)< 150 ppmForms very hard scale. Limits maximum COC.
Chlorides< 500 ppm (mild steel) < 250 ppm (SS 304)Corrosive, pitting.
Residual Oxidant0.5 – 1.0 ppmMicrobial control.

Scaling Indices

  • Langelier Saturation Index (LSI): Predicts CaCO₃ scaling tendency.
    LSI = pH – pHₛ (where pHₛ is saturation pH).
    LSI > 0: Scaling tendency. LSI < 0: Corrosive.
  • Ryznar Stability Index (RSI): Alternative. RSI ~ 6.5 is ideal.
  • Puckorius Scaling Index (PSI): Accounts for buffering capacity.

LEGIONELLA RISK MANAGEMENT

  • Critical Health Hazard.
  • Key Controls:
    • Maintain effective biocide residuals.
    • Regular system cleaning & disinfection (shock chlorination at 10+ ppm).
    • Avoid stagnant water (keep system running, design dead legs < 1 pipe diameter).
    • Temperature control: > 60°C (140°F) kills Legionella, but tower operates at 25-35°C (ideal growth range: 20-45°C).
    • Regular testing for Legionella (culture or PCR).
    • Drift control to prevent aerosolization.

TREATMENT PROGRAM IMPLEMENTATION

Step 1 – Water Analysis

  • Full analysis of make-up water and system water (pH, hardness, alkalinity, TDS, chlorides, silica, metals).
  • Baseline to determine scaling/corrosion tendencies.

Step 2 – System Audit

  • Review tower design, materials of construction, operating conditions (temperatures, cycles).
  • Identify problem areas.

Step 3 – Chemical Selection & Dosage

  • Choose appropriate scale/corrosion inhibitors and biocides.
  • Calculate feed rates based on make-up water rate and desired holding concentration.

Step 4 – Feeding Equipment

  • Chemical Feed Pumps: For continuous inhibitor feed.
  • Automatic Controllers: For oxidant feed (ORP controllers) and blowdown (conductivity controllers).
  • Day Tanks for chemical storage/dilution.

Step 5 – Monitoring & Control

  • Daily/Weekly Tests: pH, conductivity, residual biocide.
  • Monthly Tests: Full water analysis, corrosion coupons or probes.
  • Quarterly/Annually: Inspect fill, basin, heat exchanger tubes.

Step 6 – Documentation & Review

  • Maintain logs of chemical usage, test results, maintenance.
  • Review program effectiveness annually.

NON-CHEMICAL & ADVANCED TREATMENT TECHNOLOGIES

A. Physical Water Conditioning

  • Magnetic / Electronic Descalers: Claim to alter crystal structure; effectiveness debated.
  • Pulsed Power / Electrolysis: Induces precipitation for easy removal.

B. Filtration

  • Side-Stream Filtration: Continuously filters 1-10% of flow to remove suspended solids.
  • Sand Filters, Cartridge Filters, Automatic Strainers.

C. Softening & Demineralization

  • Ion Exchange Softeners: Remove calcium/magnesium (hardness) from make-up water, allow very high COC.
  • Reverse Osmosis (RO): Produces high-quality make-up water, but expensive and produces waste stream.

D. Ultraviolet (UV) Disinfection

  • Use: Supplementary for microbial control, especially Legionella. Effective for planktonic (free-floating) bacteria, not for biofilms.

E. Ozone Treatment

  • Powerful oxidizing biocide and microflocculant. Reduces chemical usage but requires capital investment and safety measures.

BEST PRACTICES SUMMARY

  1. Know Your Water: Test make-up and system water regularly.
  2. Control COC: Operate at the highest sustainable cycles.
  3. Maintain Proper pH: Usually 7.5-8.5.
  4. Use a Dual Biocide Program: Oxidizing + Non-oxidizing, with periodic shock treatment.
  5. Monitor Corrosion Rates: Use coupons or probes (< 2 mpy for mild steel, < 0.2 mpy for copper).
  6. Prevent Scale: Monitor scaling indices; use appropriate inhibitors.
  7. Clean Regularly: Mechanical cleaning of fill and basin to remove deposits and biofilm.
  8. Have a Written Water Management Plan (WMP): Especially critical for Legionella control (required by many health codes).